Mechanism of <mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML" display="inline"> <mml:msubsup> <mml:mi>E</mml:mi> <mml:mi>γ</mml:mi> <mml:mrow> <mml:msup> <mml:mi/> <mml:mo>′</mml:mo> </mml:msup> </mml:mrow> </mml:msubsup> </mml:math> defect g
Revealing the generation mechanism of oxygen-vacancy defect centers ${E}_{\ensuremath{\gamma}}^{\ensuremath{'}}$ in $a$-SiO${}_{2}$ is at the heart of hardening silicon electronics against radiation damage in extreme applications. The nature of these defect centers is not fully understood, though. This study addresses the problem using state-of-the-art first-principles calculations, and proposes a ``nonradiative carrier capture--structural relaxation'' mechanism and a fractional-power-law model to predict defect generation and evolution dynamics. The calculated defect behaviors align with experiments over wide dose and temperature ranges, and can support a range of oxygen-vacancy-related reliability and functionality studies.
Authors
- Chen Qiu (ORCID: https://orcid.org/0000-0003-4389-6671)
- Yu Jun Song (ORCID: https://orcid.org/0000-0002-9106-6333)
- Su‐Huai Wei (ORCID: https://orcid.org/0000-0003-1563-4738)
Institutions
- Eastern Institute of Technology (NZ)
- Chinese Academy of Sciences (CN)
- Xinjiang Technical Institute of Physics & Chemistry (CN)
- University of Chinese Academy of Sciences (CN)
- Eastern Institute of Technology, Ningbo
Publication Details
- Journal
- Physical Review Applied
- Published
- 2025-09-26
- DOI
- https://doi.org/10.1103/9y5y-61ps
- Citations
- 3
- Primary Topic
- Semiconductor materials and devices
- Type
- article
- Field-Weighted Citation Impact
- 2.19