Synthesis and structure of poly[(μ <sub>3</sub> -hydrogen phosphato)(pyridine)zinc(II)]
The title compound, [Zn(HPO<sub>4</sub>)(C<sub>5</sub>H<sub>5</sub>N)] <sub><i>n</i></sub> or pyZn(HPO<sub>4</sub>) (<b>1</b>), was prepared from the solvothermal reaction of [Mo<sub>3</sub>O<sub>2</sub>(O<sub>2</sub>CCH<sub>3</sub>)<sub>6</sub>(H<sub>2</sub>O)<sub>3</sub>]ZnCl<sub>4</sub> and H<sub>3</sub>PO<sub>4</sub> in a mixture of pyridine and water. It displays an infinite ladder structure built of alternately arranged ZnO<sub>3</sub>N and PO<sub>3</sub>(OH) tetra-hedra, linked O-H⋯O hydrogen bonds into supra-molecular sheets. C-H⋯O inter-actions between CH groups of the pyridine rings and phosphate groups connect the sheets into a three-dimensional framework structure.
Authors
- Zeqi Pan (ORCID: https://orcid.org/0009-0008-3911-4247)
- Qingshi Wang
- Fang Luo (ORCID: https://orcid.org/0000-0001-6198-3993)
- Xian Gang Xu
- Liming Huang
Institutions
- Fujian Medical University (CN)
- Fuzhou Second Hospital (CN)
- Second Affiliated Hospital of Fujian Medical University (CN)
Publication Details
- Journal
- Acta Crystallographica Section E Crystallographic Communications
- Published
- 2025-09-23
- DOI
- https://doi.org/10.1107/s2056989025008308
- Primary Topic
- Metal-Organic Frameworks: Synthesis and Applications
- Type
- article
- Field-Weighted Citation Impact
- 0.00