Transition-metal–free borylative functionalization of aryl fluorides with boron alkoxide in the presence of sodium dispersion
Borylative functionlization of an aryl fluoride was performed using a transition-metal-free process with sodium dispersion (SD). The reaction of 4-fluorobiphenyl with boron alkoxide (<sup>i</sup>PrOBpin) in the presence of SD afforded the borylated product in up to 62% yield. The borylation reaction proceeded with several aryl fluorides in good to excellent yields.
Authors
- Kentaro Okano (ORCID: https://orcid.org/0000-0003-2029-8505)
- Atsunori Mori (ORCID: https://orcid.org/0000-0002-1163-264X)
- Shu‐ichi Ikeda (ORCID: https://orcid.org/0000-0001-7589-6161)
- Ukyo Ogi
Institutions
- Kobe University (JP)
Publication Details
- Journal
- Chemical Communications
- Published
- 2025-01-01
- DOI
- https://doi.org/10.1039/d5cc04739k
- Primary Topic
- Organoboron and organosilicon chemistry
- Type
- article
- Field-Weighted Citation Impact
- 0.00