Practical synthesis of ferrocenyldiarylstibines and bismuthines
The reaction of <i>in situ</i>-generated lithioferrocene with pnictines EAr<sub>3</sub> (E = Sb and Bi, Ar = aryl) is presented as a reliable, robust, and practical approach for synthesising ferrocenyldiarylstibines and bismuthines. In addition to simple derivatives FcEAr<sub>2</sub> (Fc = ferrocenyl), the method enables the preparation of functional derivatives, thereby opening access to P,Sb and P,Bi-hybrids.
Authors
- Jiří Schulz (ORCID: https://orcid.org/0000-0002-5100-9975)
- David Rezazgui (ORCID: https://orcid.org/0000-0003-3066-0942)
- Petr Štěpnička (ORCID: https://orcid.org/0000-0002-5966-0578)
Institutions
- Charles University (CZ)
Publication Details
- Journal
- Chemical Communications
- Published
- 2025-01-01
- DOI
- https://doi.org/10.1039/d5cc05762k
- Primary Topic
- Ferrocene Chemistry and Applications
- Type
- article
- Field-Weighted Citation Impact
- 0.00
Funders
- Univerzita Karlova v Praze