Eco-friendly synthesis of highly emissive benzothiadiazole-based fluorophores <i>via</i> a solvent-free hand-grinding Horner–Wadsworth–Emmons reaction in ≤1 minute
We report a rapid, solvent-free hand-grinding Horner-Wadsworth-Emmons reaction that synthesizes highly emissive DS-BTD and BV-BTD derivatives within one minute. The products exhibit strong green-to-NIR fluorescence (PLQYs of up to 86.6%) and high potential when applied in OLEDs, highlighting an eco-friendly route to high-performance organic emitters.
Authors
- Po‐Heng Lin (ORCID: https://orcid.org/0000-0002-0893-0806)
- Yuan Jay Chang
- Ting-Hung Chu
- Chia‐Yu Chen (ORCID: https://orcid.org/0000-0002-8989-691X)
- Premkumar Gnanasekaran (ORCID: https://orcid.org/0000-0002-6997-8459)
Institutions
- National Chung Hsing University (TW)
- Tunghai University (TW)
Publication Details
- Journal
- Chemical Communications
- Published
- 2025-01-01
- DOI
- https://doi.org/10.1039/d5cc04892c
- Citations
- 1
- Primary Topic
- Inorganic and Organometallic Chemistry
- Type
- article
- Field-Weighted Citation Impact
- 0.94