Tuneable phosphorescence and singlet oxygen production of bridged ethers <i>via</i> chalcogen variation and photocyclisation

In this contribution, we merged a motif for solution and solid-state emission (SSSE) with thioethers capable of photocyclisation to combine efficient emission across several states of aggregation with tuneable phosphorescence. In addition, the bridged ethers revealed remarkable singlet oxygen quantum yields that increase with the chalcogen's atomic number.

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Publication Details

Journal
Chemical Communications
Published
2025-01-01
DOI
https://doi.org/10.1039/d5cc05206h
Primary Topic
Radical Photochemical Reactions
Type
article
Field-Weighted Citation Impact
0.00

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article

Tuneable phosphorescence and singlet oxygen production of bridged ethers via chalcogen variation and photocyclisation

Jens Voskuhl, Christoph Wölper, Anzhela Galstyan, Marco Schmiedtchen et al.
Chemical Communications
Radical Photochemical Reactions
article

Tuneable phosphorescence and singlet oxygen production of bridged ethers via chalcogen variation and photocyclisation

Jens Voskuhl, Christoph Wölper, Anzhela Galstyan, Marco Schmiedtchen, Thulaseedharan Nair Sailaja Sidharth
article en

Abstract

In this contribution, we merged a motif for solution and solid-state emission (SSSE) with thioethers capable of photocyclisation to combine efficient emission across several states of aggregation with tuneable phosphorescence. In addition, the bridged ethers revealed remarkable singlet oxygen quantum yields that increase with the chalcogen's atomic number.

Chemical CommunicationsVol. 61(95)
University of Duisburg-Essen (DE)
Deutsche Forschungsgemeinschaft
Openalex Percentile: Top 77%
Radical Photochemical Reactions
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