Confinement-driven renormalization of magnon and phonon spectra in <mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML"> <mml:mrow> <mml:msub> <mml:mi>Fe</mml:mi> <mml:mn>3</mml:mn> </mml:msub> <mml:msub> <mml:mi mathvariant="normal">O</mml:mi> <
The authors reveal here how finite-size confinement reshapes spin and lattice excitations in Fe${}_{3}$O${}_{4}$ nanoparticles using time-of-flight neutron spectroscopy and numerical simulations. Confinement induces surface strain that softens and broadens optical phonons, while surface exchange disorder suppresses acoustic magnon velocities. Molecular dynamics captures size-dependent phonon renormalization, and a reduced-exchange spin-wave model reproduces the magnon behavior. These results establish confinement as a powerful route to tailor spin dynamics and thermal transport in magnetic nanomaterials.
Authors
- Dehong Yu (ORCID: https://orcid.org/0000-0003-2995-0336)
- Zhenxiang Cheng (ORCID: https://orcid.org/0000-0003-4847-2907)
- Pablo Galaviz (ORCID: https://orcid.org/0000-0001-7170-3166)
- K. C. Rule (ORCID: https://orcid.org/0000-0001-9534-2350)
- David Cortie (ORCID: https://orcid.org/0000-0003-2383-1619)
- Kyle A. Portwin (ORCID: https://orcid.org/0009-0008-4421-949X)
Institutions
- Australian Nuclear Science and Technology Organisation (AU)
- University of Wollongong (AU)
Publication Details
- Journal
- Physical review. B./Physical review. B
- Published
- 2025-10-07
- DOI
- https://doi.org/10.1103/15zz-8g6x
- Citations
- 1
- Primary Topic
- Multiferroics and related materials
- Type
- article
- Field-Weighted Citation Impact
- 0.43