Room-temperature chromatographic H <sub>2</sub> /D <sub>2</sub> separation <i>via</i> a solid dihydrogen complex with balanced thermodynamics and kinetics
Mn-PCy3 showed the highest H 2 /D 2 separation ability among known materials due to a large difference in ZPVE. D 2 separation with pressure swing adsorption using Mn-PCy3 could be achieved with ∼1/10 of the energy cost for distillation.
Authors
- Shin‐ichiro Noro (ORCID: https://orcid.org/0000-0003-4757-4741)
- Kaiji Uchida
- Ryojun Toyoda (ORCID: https://orcid.org/0000-0002-0168-0533)
- Tamon Yamauchi
- Naoki Kishimoto (ORCID: https://orcid.org/0000-0003-2988-456X)
- Hiroaki Iguchi (ORCID: https://orcid.org/0000-0001-5368-3157)
- Ryota Sakamoto (ORCID: https://orcid.org/0000-0002-8702-1378)
- Shinya Takaishi (ORCID: https://orcid.org/0000-0002-6739-8119)
- Hao Xue
- Taku Kitayama
- Nino Keuzenkamp
Institutions
- Tohoku University (JP)
- Hokkaido University (JP)
- SPring-8 (JP)
- RIKEN (JP)
- Tokyo Metropolitan Industrial Technology Research Institute (JP)
- Nagoya University (JP)
Publication Details
- Journal
- Green Chemistry
- Published
- 2025-10-23
- DOI
- https://doi.org/10.1039/d5gc04476f
- Citations
- 1
- Primary Topic
- Catalysis and Oxidation Reactions
- Type
- article
- Field-Weighted Citation Impact
- 0.39
Funders
- Institute for Quantum Chemical Exploration
- ENEOS Hydrogen Trust Fund
- Japan Society for the Promotion of Science
- Japan Science and Technology Agency