Vitrimer-like acrylic glass with fast stress relaxation by high-speed carboxy exchange reaction

Vitrimer-like acrylic glass cross-linked via 2-(acyloxymethyl)acrylate moieties was synthesized, which exhibited rapid stress relaxation with a relaxation time of 5 s at 140 °C owing to fast carboxy exchange via a conjugate substitution reaction.

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Publication Details

Journal
RSC Applied Polymers
Published
2025-10-22
DOI
https://doi.org/10.1039/d5lp00241a
Primary Topic
Advanced Theoretical and Applied Studies in Material Sciences and Geometry
Type
article
Field-Weighted Citation Impact
0.00

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article

Vitrimer-like acrylic glass with fast stress relaxation by high-speed carboxy exchange reaction

Mikihiro Hayashi, Yasuhiro Kohsaka, Miu Mizuma
RSC Applied Polymers
Advanced Theoretical and Applied Studies in Material Sciences and Geometry
article

Vitrimer-like acrylic glass with fast stress relaxation by high-speed carboxy exchange reaction

Mikihiro Hayashi, Yasuhiro Kohsaka, Miu Mizuma
article en

Abstract

Vitrimer-like acrylic glass cross-linked via 2-(acyloxymethyl)acrylate moieties was synthesized, which exhibited rapid stress relaxation with a relaxation time of 5 s at 140 °C owing to fast carboxy exchange via a conjugate substitution reaction.

RSC Applied PolymersVol. 4(1)
Shinshu University (JP), Nagoya Institute of Technology (JP)
Precursory Research for Embryonic Science and Technology
Openalex Percentile: Top 71%
Advanced Theoretical and Applied Studies in Material Sciences and Geometry
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Vitrimer-like acrylic glass with fast stress relaxation by high-speed carboxy exchange reaction — Mikihiro Hayashi, Yasuhiro Kohsaka, et al. · RSC Applied Polymers (2025) | TGRS Research Map | TGRS