Nanoscale infrared investigation and chemical associations of organic matter in Asuka 12236

Abstract CM chondrites have undergone varying degrees of aqueous alteration and thermal metamorphism on their parent bodies. Consequently, the petrologic grade of CM chondrites spans the entire type 2 scale (e.g., types 2.0–2.9). A 12236 is a very primitive petrologic type 2.9 carbonaceous chondrite that offers a unique window into the complex formation and evolution histories of CM chondrites. Based on its chemical composition, it is one of the least altered CM chondrites identified to date and one of the most primitive meteorites. Here, we present a comprehensive characterization of the organic and inorganic constituents of A 12236, determined through electron microscopy, micro‐Raman, and s‐SNOM nano‐FT‐IR spectroscopy. We identified FeNiS phases, including pentlandite, pyrrhotite, and troilite, within a fine‐grained matrix composed predominantly of crystalline and amorphous silicates, including phyllosilicates. Raman spectroscopic results suggest that A 12236 experienced less thermal metamorphism than type 3 carbonaceous chondrites and contains polyaromatic organic matter with slightly differing structural order. Nano‐FT‐IR spectroscopy revealed chemically distinct aliphatic and aromatic organic phases, with observed compositional heterogeneity indicating variations in organic precursors and accreted materials. Correlation analysis highlights the complex associations between organic matter and phyllosilicates, along with evidence of differing aromatic compositions within the matrix. The varying abundances of nanoscale organics in different areas of A 12236 suggest that the organic matter is highly heterogeneously distributed within the matrix. Our findings demonstrate the effectiveness of nano‐FT‐IR spectroscopy for high‐resolution, nondestructive analysis of extraterrestrial samples.