Evolution Mechanism and Thermal Transport Properties of Surface-Activated Bonded SiC/SiC Interfaces

The driver control chips for high-power silicon carbide (SiC) power devices rely on silicon-based CMOS processes, which lead to parasitic effects and thermal management bottlenecks. Customisable design of nanotransition layers for SiC surface-activated bonding (SAB) has demonstrated significant application value. However, current SAB research focuses on process validation of specific material combinations and lacks understanding of the underlying principles governing surface-activated bond design. The experimental findings suggest that the sputtering-deposition time, rather than the Ar atom bombardment time, plays a pivotal role in the control of the bonding interface. In the initial stage of sputtering-deposition, the deposited layer exhibits a low density, leading to a thicker and inferior interface. As time increased, the deposited layer undergoes a gradual densification process, ultimately resulting in the formation of Fe single-crystal interfaces and the establishment of atomic-level bonding between Fe and SiC. Molecular dynamics simulations confirm the fracture mechanism at the single-crystal SiC/Fe/SiC interface, where fracture occurs within the Fe transition layer. In addition, the interfacial thermal resistance of SiC/Fe/SiC interface (4.53 m<sup>2</sup>K/GW) is lower than that of the thinner amorphous carbon SiC/a-C/SiC interface (6.74 m<sup>2</sup>K/GW). The present work reveals a universal theoretical framework for expanding the application of surface activation bonding technology in power module packaging, photonic integration, and other fields.

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Publication Details

Journal
ACS Applied Materials & Interfaces
Published
2025-10-21
DOI
https://doi.org/10.1021/acsami.5c11466
Primary Topic
Thermal properties of materials
Type
article
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article

Evolution Mechanism and Thermal Transport Properties of Surface-Activated Bonded SiC/SiC Interfaces

Wenbo Hu, Bo Song, Yongfeng Qu, Xinlong Zhao et al.
ACS Applied Materials & Interfaces
Thermal properties of materials
article

Evolution Mechanism and Thermal Transport Properties of Surface-Activated Bonded SiC/SiC Interfaces

Wenbo Hu, Bo Song, Yongfeng Qu, Xinlong Zhao, Ningkang Deng, Jin Yuan, Hongxing Wang, Zhaoyang Zhang
article en

Abstract

The driver control chips for high-power silicon carbide (SiC) power devices rely on silicon-based CMOS processes, which lead to parasitic effects and thermal management bottlenecks. Customisable design of nanotransition layers for SiC surface-activated bonding (SAB) has demonstrated significant application value. However, current SAB research focuses on process validation of specific material combinations and lacks understanding of the underlying principles governing surface-activated bond design. The experimental findings suggest that the sputtering-deposition time, rather than the Ar atom bombardment time, plays a pivotal role in the control of the bonding interface. In the initial stage of sputtering-deposition, the deposited layer exhibits a low density, leading to a thicker and inferior interface. As time increased, the deposited layer undergoes a gradual densification process, ultimately resulting in the formation of Fe single-crystal interfaces and the establishment of atomic-level bonding between Fe and SiC. Molecular dynamics simulations confirm the fracture mechanism at the single-crystal SiC/Fe/SiC interface, where fracture occurs within the Fe transition layer. In addition, the interfacial thermal resistance of SiC/Fe/SiC interface (4.53 m<sup>2</sup>K/GW) is lower than that of the thinner amorphous carbon SiC/a-C/SiC interface (6.74 m<sup>2</sup>K/GW). The present work reveals a universal theoretical framework for expanding the application of surface activation bonding technology in power module packaging, photonic integration, and other fields.

ACS Applied Materials & InterfacesVol. 17(44)
Missile Defense Agency (US), Air Force Engineering University (CN), Xi'an Jiaotong University (CN)
Openalex Percentile: Top 76%
Thermal properties of materials
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