Tetrahydroxydiboron-Mediated Synthesis of α-Sulfonyl Ketoximes from Nitroalkenes and Sodium Sulfinates
A tetrahydroxydiboron-mediated facile synthesis of α-sulfonyl ketoximes from nitroalkenes and sodium sulfinates was developed. In this reaction, the oximes were formed through the reduction of nitro and avoided the utilization of an external NO source. This reaction features mild reaction conditions, gram-scale synthesis, broad substrate scope, and good functional group tolerance.
Authors
- Haijun Yu (ORCID: https://orcid.org/0000-0002-3398-0880)
- Ya‐Jung Cheng (ORCID: https://orcid.org/0000-0001-9150-4690)
- Ablimit Abdukader
- Yonghong Zhang (ORCID: https://orcid.org/0000-0002-7740-9408)
- Kun Xia (ORCID: https://orcid.org/0000-0002-5667-4042)
- Yuqing Zhao
- Z. S. Shan
Institutions
- Xinjiang University (CN)
Publication Details
- Journal
- The Journal of Organic Chemistry
- Published
- 2025-10-21
- DOI
- https://doi.org/10.1021/acs.joc.5c01425
- Primary Topic
- Sulfur-Based Synthesis Techniques
- Type
- article
- Field-Weighted Citation Impact
- 0.00