Air-stable tetraphenylporphyrinate–Cp* sandwiches of Ln( <scp>iii</scp> ): how decisive is geometry in controlling magnetic anisotropy?
The first air-stable sandwich complexes TPPLnCp* (Ln = Y, Tb, Dy, Ho, and Er) containing tetraphenylporphyrinate and pentamethylcyclopentadienide ligands were synthesized. Tb 3+ , Dy 3+ , and Er 3+ derivatives are field-induced single-molecule magnets.
Authors
- Dmitry M. Lyubov (ORCID: https://orcid.org/0000-0001-8472-3764)
- Joulia Larionova≠ (ORCID: https://orcid.org/0000-0002-3279-9158)
- Gayane A. Kirakosyan (ORCID: https://orcid.org/0000-0002-5801-2827)
- Veacheslav Vieru (ORCID: https://orcid.org/0000-0001-6375-4537)
- Yannick Guari≠ (ORCID: https://orcid.org/0000-0001-5205-3225)
- Alexander G. Martynov (ORCID: https://orcid.org/0000-0002-2192-7134)
- Gautier Félix≠ (ORCID: https://orcid.org/0000-0002-2761-6353)
- Yulia G. Gorbunova (ORCID: https://orcid.org/0000-0002-2333-4033)
- Yulia Vladimirovna Nelyubina (ORCID: https://orcid.org/0000-0002-9121-0040)
- Анна В. Вологжанина (ORCID: https://orcid.org/0000-0002-6228-303X)
- Tatyana V. Mahrova
- A.A. Trifonov
- Saad Sene
- ilya ermolin
- Max Kallio
Institutions
- École Nationale Supérieure de Chimie de Montpellier (FR)
- Centre National de la Recherche Scientifique (FR)
- Université de Montpellier (FR)
- A. N. Nesmeyanov Institute of Organoelement Compounds (RU)
- Maastricht University (NL)
- Frumkin Institute of Physical Chemistry and Electrochemistry Russian Academy of Sciences (RU)
- NS Kurnakova Institute of General and Inorganic Chemistry (RU)
- G.A. Razuvaev Institute of Organometallic Chemistry (RU)
Publication Details
- Journal
- Inorganic Chemistry Frontiers
- Published
- 2025-10-21
- DOI
- https://doi.org/10.1039/d5qi01611h
- Primary Topic
- Magnetism in coordination complexes
- Type
- article
- Field-Weighted Citation Impact
- 0.00