Enhanced nitrate removal from aqueous solutions using amine-functionalized biowaste-derived adsorbent

Nitrate ions constitute one of the major nitrogen resources for plant growth. However, the large amount of nitrate ions released into nearby waterbodies could cause eutrophication problems. This study developed a bio-based adsorbent from biowaste materials and functionalized it with amine groups through the Mannich reaction. The successful modification was confirmed using FTIR, SEM, and elemental analysis. Batch adsorption experiments were conducted under varying conditions, including contact time, pH, and initial nitrate concentration. Results showed that the amine-functionalized bio-adsorbent exhibited an enhanced capacity for nitrate removal, with a maximum adsorption capacity of 65.79 mg g<sup>-1</sup>. Electrostatic interactions between amine-functionalized bio-adsorbent and nitrate ions were identified as the dominant sorption mechanism. These findings highlight the potential of this bio-based adsorbent as a sustainable and effective solution for nitrate removal from contaminated water sources.

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Publication Details

Journal
Scientific Reports
Published
2025-10-21
DOI
https://doi.org/10.1038/s41598-025-17259-9
Citations
1
Primary Topic
Adsorption and biosorption for pollutant removal
Type
article
Field-Weighted Citation Impact
0.82

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article

Enhanced nitrate removal from aqueous solutions using amine-functionalized biowaste-derived adsorbent

Lang Liu, Tiantian Li, Meng Li, Ying Li
1 citations
Scientific Reports
Adsorption and biosorption for pollutant removal
0.82
article

Enhanced nitrate removal from aqueous solutions using amine-functionalized biowaste-derived adsorbent

Lang Liu, Tiantian Li, Meng Li, Ying Li
article en
1 citations

Abstract

Nitrate ions constitute one of the major nitrogen resources for plant growth. However, the large amount of nitrate ions released into nearby waterbodies could cause eutrophication problems. This study developed a bio-based adsorbent from biowaste materials and functionalized it with amine groups through the Mannich reaction. The successful modification was confirmed using FTIR, SEM, and elemental analysis. Batch adsorption experiments were conducted under varying conditions, including contact time, pH, and initial nitrate concentration. Results showed that the amine-functionalized bio-adsorbent exhibited an enhanced capacity for nitrate removal, with a maximum adsorption capacity of 65.79 mg g<sup>-1</sup>. Electrostatic interactions between amine-functionalized bio-adsorbent and nitrate ions were identified as the dominant sorption mechanism. These findings highlight the potential of this bio-based adsorbent as a sustainable and effective solution for nitrate removal from contaminated water sources.

Scientific ReportsVol. 15(1)
Xi'an University of Science and Technology (CN), Ministry of Education of the People's Republic of China (CN)
National Natural Science Foundation of China
Openalex Percentile: Top 22%
Adsorption and biosorption for pollutant removal
0.82
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Enhanced nitrate removal from aqueous solutions using amine-functionalized biowaste-derived adsorbent — Lang Liu, Tiantian Li, et al. · Scientific Reports (2025) | TGRS Research Map | TGRS