Dual-Functional Paper with Anti-Photodegradation and Acidification Resistance Enabled by Carbon Quantum Dots@Mg(OH) <sub>2</sub> Nanocomposite
Paper-based cultural relics possess great historical and cultural value but are vulnerable to irreversible degradation from high-energy ultraviolet (UV) light exposure and acidification, threatening their long-term preservation. Current paper protection predominantly relies on exogenous materials with single functions, which not only provide limited protective effects but also pose a risk of secondary damage. In this study, we developed a Dual-Functional paper by directly integrating a carbon quantum dot–magnesium hydroxide (CQDs@Mg(OH)2) nanocomposite into the papermaking process, thereby endowing the paper with intrinsic resistance to both acidification and UV-induced photodegradation, which reduces the reliance on subsequent protective treatments and fundamentally enhances the paper’s longevity. The results demonstrate that the functional paper integrated with CQDs@Mg(OH)2 nanocomposites shows good structural compatibility and strong resistance to degradation. Under the conditions of both UV exposure and dry-heat aging, the functional paper demonstrates excellent resistance to photooxidative and acid-induced degradation, indicating its strong potential for extending the longevity of paper-based materials. Additionally, the fluorescent properties of CQDs reveal promising potential as optical anticounterfeiting markers. This work opens an avenue for the design of long-lasting functional paper enabled by carbon-based materials, with promising applications in the preservation of paper-based cultural heritage.
Authors
- Zhenyu Dai (ORCID: https://orcid.org/0000-0001-6135-7749)
- Yizhuo Li (ORCID: https://orcid.org/0009-0004-8871-192X)
- Sinong Wang (ORCID: https://orcid.org/0000-0002-6191-4952)
- Jinchan Zhao
- Shiliang Mei (ORCID: https://orcid.org/0000-0001-7148-2906)
- Wanlu Zhang (ORCID: https://orcid.org/0000-0002-7119-1874)
- Ruiqian Guo (ORCID: https://orcid.org/0000-0002-0498-0363)
- Mingliang Zhang (ORCID: https://orcid.org/0000-0002-6421-7730)
- Bojun Zhang (ORCID: https://orcid.org/0009-0008-8159-5822)
Institutions
- Fudan University (CN)
- Heritage Preservation (US)
- Robotics Research (United States) (US)
Publication Details
- Journal
- ACS Applied Nano Materials
- Published
- 2025-10-20
- DOI
- https://doi.org/10.1021/acsanm.5c03656
- Primary Topic
- Carbon and Quantum Dots Applications
- Type
- article
- Field-Weighted Citation Impact
- 0.00