Elucidation of Electrical Characteristics for Apples (Malus domestica) Using Electrochemical Impedance Spectroscopy

Dielectric characterization offers valuable insights into fruit structure, ripening, and storage stability. However, systematic studies on apples are still limited. This work elucidates the electrical and physicochemical properties of a specific variety of apples, Malus domestica, using Electrochemical Impedance Spectroscopy (EIS), a non-destructive, fast and cost-effective technique, suitable for real-time quality assessments. The apple samples were analyzed over the frequency range of 20 Hz–120 MHz at 25 °C, and impedance data were modeled using equivalent circuits and dielectric relaxation models. Physicochemical analyses confirmed a high moisture content (84%, wwb), pH 4.81, TSS 14.58 °Brix, and acidity 0.64%, which is typical of fresh Red Delicious apples. Impedance spectra revealed semicircular and Warburg elements in Nyquist plots, indicating resistive, capacitive, and diffusive processes. Equivalent circuit fitting with the proposed R-C-Warburg impedance model outperformed (R2 = 0.9946 and RMSE = 6.610) the classical Cole and Double-Shell models. The complex permittivity (ε) represented a frequency-dependent ionic diffusion, space-charge polarization, and dipolar relaxation decay, while electrical modulus analysis highlighted polarization and charge carrier dynamics. The translational hopping of charge carriers was confirmed through AC conductivity following Jonscher’s power law with an exponent of ƞ = 0.627. These findings establish a comprehensive dielectric profile and advanced circuit fitting for biological tissues, highlighting a promising non-invasive approach using EIS for real-time monitoring of fruit quality, with direct applications in post-harvest storage, supply chain management, and non-destructive quality assurance in the food industry.