The catalytic activity of modified KIT-6@Fe3O4 decorated with Pd for the preparation of biaryls and aromatic amines

KIT-6 mesoporous and Fe 3 O 4 were used to create a novel hybrid (magnetic and mesoporous) solid material. Modifying the surface of Fe 3 O 4 @SiO 2 @KIT-6 with ortho-phenylenediamine, followed by decoration with palladium, produced a novel magnetic mesoporous hybrid nanomaterial (Fe 3 O 4 @SiO 2 @KIT-6@ o -PDA-Pd 0 ). Fe 3 O 4 @SiO 2 @KIT-6@ o -PDA-Pd 0 was employed as a catalyst to produce biaryls and aromatic amines in a highly effective, heterogeneous, and recyclable manner. The characterization of this magnetic mesoporous material has been conducted using various analytical techniques, including FT-IR, SEM, AAS, XRD, TGA, VSM, and N 2 adsorption-desorption. • Fe 3 O 4 @SiO 2 @KIT-6@ o -PDA-Pd 0 is introduced as a novel mesoporous magnetic catalyst. • Fe 3 O 4 @SiO 2 @KIT-6@ o -PDA-Pd 0 characterized by FT-IR, SEM, AAS, XRD, TGA, VSM, and N 2 adsorption-desorption methods. • Fe 3 O 4 @SiO 2 @KIT-6@ o -PDA-Pd 0 is composed of non-toxic materials, ensuring environmental friendliness. • An efficient catalytic method has been presented for the synthesis of biaryls and anilines.

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Publication Details

Journal
Applied Catalysis O Open
Published
2025-10-19
DOI
https://doi.org/10.1016/j.apcato.2025.207079
Primary Topic
Nanomaterials for catalytic reactions
Type
article
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article

The catalytic activity of modified KIT-6@Fe3O4 decorated with Pd for the preparation of biaryls and aromatic amines

Zahra Moradi, Arash Ghorbani‐Choghamarani
Applied Catalysis O Open
Nanomaterials for catalytic reactions
article

The catalytic activity of modified KIT-6@Fe3O4 decorated with Pd for the preparation of biaryls and aromatic amines

Zahra Moradi, Arash Ghorbani‐Choghamarani
article en

Abstract

KIT-6 mesoporous and Fe 3 O 4 were used to create a novel hybrid (magnetic and mesoporous) solid material. Modifying the surface of Fe 3 O 4 @SiO 2 @KIT-6 with ortho-phenylenediamine, followed by decoration with palladium, produced a novel magnetic mesoporous hybrid nanomaterial (Fe 3 O 4 @SiO 2 @KIT-6@ o -PDA-Pd 0 ). Fe 3 O 4 @SiO 2 @KIT-6@ o -PDA-Pd 0 was employed as a catalyst to produce biaryls and aromatic amines in a highly effective, heterogeneous, and recyclable manner. The characterization of this magnetic mesoporous material has been conducted using various analytical techniques, including FT-IR, SEM, AAS, XRD, TGA, VSM, and N 2 adsorption-desorption. • Fe 3 O 4 @SiO 2 @KIT-6@ o -PDA-Pd 0 is introduced as a novel mesoporous magnetic catalyst. • Fe 3 O 4 @SiO 2 @KIT-6@ o -PDA-Pd 0 characterized by FT-IR, SEM, AAS, XRD, TGA, VSM, and N 2 adsorption-desorption methods. • Fe 3 O 4 @SiO 2 @KIT-6@ o -PDA-Pd 0 is composed of non-toxic materials, ensuring environmental friendliness. • An efficient catalytic method has been presented for the synthesis of biaryls and anilines.

Applied Catalysis O OpenVol. 209
Bu-Ali Sina University (IR), Ilam University (IR)
Openalex Percentile: Top 77%
Nanomaterials for catalytic reactions
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The catalytic activity of modified KIT-6@Fe3O4 decorated with Pd for the preparation of biaryls and aromatic amines — Zahra Moradi, Arash Ghorbani‐Choghamarani · Applied Catalysis O Open (2025) | TGRS Research Map | TGRS