DYNAMICS OF RESIDENTIAL INDOOR GAS- AND PARTICLE-PHASE WATER-SOLUBLE ORGANIC CARBON: MEASUREMENTS DURING THE CASA EXPERIMENT

Previous time-integrated (2 h to 4 h) measurements show that total gas-phase water-soluble organic carbon (WSOCg) is 10 to 20 times higher inside homes compared to outside. However, concentration dynamics of WSOCg and total particle phase WSOC (WSOCp)-are not well understood. During the Chemical Assessment of Surfaces and Air (CASA) experiment, we measured concentration dynamics of WSOCg and WSOCp inside a residential test facility in the house background and during scripted activities. A total organic carbon (TOC) analyzer pulled alternately from a particle-into-liquid sampler (PILS) or a mist chamber (MC). WSOCg concentrations (215 ± 29 μg-C m-3) were generally 36× higher than WSOCp (6 ± 3 μg-C m-3) and 20× higher than outdoor levels. A building-specific emission factor (Ef) of 31 mg-C h-1 maintained the relatively high house WSOCg background, which was dominated by ethanol (46 μg-C m-3 to 82 μg-C m-3). When we opened the windows, WSOCg decayed slower (2.8 h-1) than the air change rate (21.2 h-1) and Ef increased (243 mg-C h-1). The response (increased Ef) suggests WSOCg concentrations are regulated by large near surface reservoirs rather than diffusion through surface materials. Cooking and ozone addition had a small impact on WSOC, whereas surface cleaning, volatile organic compound (VOC) additions, or wood smoke injections had significant impacts on WSOC concentrations. WSOCg concentration decay rates from these activities (0.4 h-1 to 4.0 h-1) were greater than the normal operating 0.24 h-1 air change rate, which is consistent with an important role for surface removal.