Synergistic Integration Nanoarchitectonics of Zn-MOF and Poly(1-Amino-9, 10-anthraquinone) for Enhanced Capacitor Performance

Abstract The increasing concern regarding energy demand has emerged as a significant issue for various industries, including industry and transportation. Capacitors have recently emerged as a novel approach to address the worldwide energy shortage. Consequently, we have created novel materials for capacitor uses. A composite of poly aminoanthraquinone (PAAQ) and Zinc-based metal organic framework (Zn-MOF) was employed for high-capacitance applications. Comparative studies were conducted on PAAQ and Zn-MOF. Accordingly, Zn-MOF was added to PAAQ using both layer structure (GC/PAAQ/Zn-MOF and physical mixing (GC/PAAQ-Zn-MOF). The modified glassy carbon electrode’s structure and morphology were examined using X-ray diffraction (XRD), Fourier Transform Infrared Spectroscopy (FT-IR), Scanning Electron Microscopy (SEM), Energy Dispersive X-ray Analysis (EDAX), Elemental Mapping, and Ultraviolet-Visible Spectroscopy (UV-Vis). The modified electrodes exhibited a high capacitance when examined in 1.0 M H 2 SO 4 equal 180, 298, and 330 F/g@1 A/g for GC/PAAQ, GC/PAAQ/Zn-MOF, and GC/PAAQ-Zn-MOF; respectively. Furthermore, the rate of capability was calculated as 81, 71, and 91% for GC/PAAQ, GC/PAAQ/Zn-MOF, and GC/PAAQ-Zn-MOF, respectively.

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Publication Details

Journal
Journal of Inorganic and Organometallic Polymers and Materials
Published
2025-10-18
DOI
https://doi.org/10.1007/s10904-025-04054-2
Primary Topic
Supercapacitor Materials and Fabrication
Type
article
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article

Synergistic Integration Nanoarchitectonics of Zn-MOF and Poly(1-Amino-9, 10-anthraquinone) for Enhanced Capacitor Performance

Mahmoud A. Hefnawy, Shymaa S. Medany, Khaled M. Ismail, Safaa Shawky Hassan
Journal of Inorganic and Organometallic Polymers and Materials
Supercapacitor Materials and Fabrication
article

Synergistic Integration Nanoarchitectonics of Zn-MOF and Poly(1-Amino-9, 10-anthraquinone) for Enhanced Capacitor Performance

Mahmoud A. Hefnawy, Shymaa S. Medany, Khaled M. Ismail, Safaa Shawky Hassan
article en

Abstract

Abstract The increasing concern regarding energy demand has emerged as a significant issue for various industries, including industry and transportation. Capacitors have recently emerged as a novel approach to address the worldwide energy shortage. Consequently, we have created novel materials for capacitor uses. A composite of poly aminoanthraquinone (PAAQ) and Zinc-based metal organic framework (Zn-MOF) was employed for high-capacitance applications. Comparative studies were conducted on PAAQ and Zn-MOF. Accordingly, Zn-MOF was added to PAAQ using both layer structure (GC/PAAQ/Zn-MOF and physical mixing (GC/PAAQ-Zn-MOF). The modified glassy carbon electrode’s structure and morphology were examined using X-ray diffraction (XRD), Fourier Transform Infrared Spectroscopy (FT-IR), Scanning Electron Microscopy (SEM), Energy Dispersive X-ray Analysis (EDAX), Elemental Mapping, and Ultraviolet-Visible Spectroscopy (UV-Vis). The modified electrodes exhibited a high capacitance when examined in 1.0 M H 2 SO 4 equal 180, 298, and 330 F/g@1 A/g for GC/PAAQ, GC/PAAQ/Zn-MOF, and GC/PAAQ-Zn-MOF; respectively. Furthermore, the rate of capability was calculated as 81, 71, and 91% for GC/PAAQ, GC/PAAQ/Zn-MOF, and GC/PAAQ-Zn-MOF, respectively.

Journal of Inorganic and Organometallic Polymers and Materials
Cairo University (EG)
Openalex Percentile: Top 80%
Supercapacitor Materials and Fabrication
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