Enhancing the Output Performance of Fiber-TENG Through Graphite Doping and Its Application in Human Motion Sensing

Triboelectric nanogenerators (TENG) are mechanical energy harvesters characterized by high sensitivity and simple structure and are currently being widely developed for use in human body motion sensing. Among them, fiber-based TENGs (FTENG) are particularly suitable for wearable human motion sensors due to their unique structure, which offers flexibility, high durability, and comfort. However, studies involving doping to further modify the electrical output characteristics of FTENGs are very limited. Here, we propose an innovative approach that combines graphite (GP) doping with fiber-based TENG fabrication, successfully developing a graphite-doped polyester fiber-based TENG (GP@PET-TENG). Proper graphite doping can increase the amount of transferred charge and thus improve the output electrical performance of TENG, but this method has rarely been explored in FTENG. With the incorporation of 3%wt graphite, the open-circuit voltage of the GP@PET-TENG increased from 103.3 V to 202.1 V, and the short-circuit current increased from 60.7 μA to 105.1 μA, compared to the pure polyester fiber based TENG (PET-TENG). The device achieved a maximum output power of 4.15 mW (2.59 W/m²), demonstrates the capability to charge various capacitors, and successfully lit up 200 LEDs. By attaching the GP@PET tribo-layer to human skin, a single-electrode mode TENG can be formed, which captures the subject's motion signals through skin contact and separation, converting them into voltage outputs. In fist-clenching and wrist-bending tests, motion-induced voltage signals up to 0.6 V were recorded, demonstrating the potential applications in rehabilitation assistance and mechanical control.