Ligand-centered redox-driven Zn( <scp>ii</scp> )-catalyzed anti-Markovnikov hydroamination of activated alkenes with primary aromatic amines <i>via</i> aminium radical cations
Anti-Markovnikov hydroamination of activated alkenes with primary aromatic amines is reported using a Zn( ii )-catalyst bearing a redox-noninnocent azo moiety, wherein amine to ligand single electron transfer generates the aminium radical cations.
Authors
- Azra Pervin
- Santana Chakraborty (ORCID: https://orcid.org/0009-0007-4673-0446)
- Subhasree Pal
- Nanda Dulal Paul (ORCID: https://orcid.org/0000-0002-8872-1413)
Institutions
- Indian Institute of Engineering Science and Technology, Shibpur (IN)
Publication Details
- Journal
- Organic Chemistry Frontiers
- Published
- 2025-10-17
- DOI
- https://doi.org/10.1039/d5qo01248a
- Citations
- 1
- Primary Topic
- Oxidative Organic Chemistry Reactions
- Type
- article
- Field-Weighted Citation Impact
- 0.94