Observationally-derived Fractional Release Factors, Ozone Depletion Potentials, and Stratospheric Lifetimes of Four Long-Lived CFCs: CFC-13 (CClF ₃ ), CFC-114 (C ₂ Cl ₂ F ₄ ), CFC-114a (CF ₃ CCl

Abstract. The longer an Ozone Depleting Substance (ODS) remains in the stratosphere, the longer it will be available for the process of ozone depletion. We present improved policy-relevant parameters: Fractional Release Factors (FRFs), Ozone Depletion Potentials (ODPs), and stratospheric lifetimes, for four understudied long-lived chlorofluorocarbons (CFCs): CFC-13 (CClF3), CFC-114 (CClF2CCClF2), CFC-114a (CCl2FCF3), and CFC-115 (C2ClF5). Previous estimates for the stratospheric lifetimes of these compounds were derived using model and laboratory-based kinetic studies. This study instead uses stratospheric observational data, and correlations between FRFs and lifetimes, to semi-empirically and independently determine the steady-state stratospheric lifetimes of these compounds. Our newly derived stratospheric lifetime estimates are 315 (287–331) yr for CFC-13 (300+ years shorter than previous estimates), 190 (176–201) yr for CFC-114 (1 year shorter than previous estimates), 81 (7687) yr for CFC-114a (25.7 years shorter), and 369 (328–435) yr for CFC-115 (295 years shorter). For CFC-13 and CFC-115 this is outside the uncertainty ranges of previously published estimates. This suggests that these two compounds may have had greater emissions than previously thought, in order to account for their abundance. We calculated FRFs and ODSs for the four CFCs of interest: CFC-13 (FRF = 0.07, ODP = 0.4), CFC-114 (FRF = 0.12, ODP = 0.5), CFC-114a (FRF = 0.31, ODP = 0.52), and CFC-115 (FRF = 0.06, ODP = 0.27). Providing new and updated lifetimes, FRFs and ODPs for these compounds, will help improve future estimates of their tropospheric emissions and their potential resulting damage to the stratospheric ozone layer.