Advances in Synergistic Corrosion Mechanisms of and Management Strategies for Impurity Gases During Supercritical CO2 Pipeline Transportation

Supercritical CO₂ (sCO₂) pipeline transport is a critical link for the large-scale implementation of Carbon Capture, Utilization, and Storage (CCUS) technology, yet its safety is severely challenged by residual impurity gases (e.g., H₂O, O₂, SO₂, H₂S, and NO₂) from the capture process. This review systematically consolidates recent research advances, with the key findings being the following. Firstly, it reveals that the nonlinear synergistic effects among impurities are the primary cause of uncontrolled corrosion, whose destructive impact far exceeds the simple sum of individual effects. Secondly, it delineates the specific roles and critical thresholds of different impurities within the corrosion chain reaction, providing a theoretical basis for targeted control. Consequently, engineering management must enforce strict impurity concentration thresholds integrated with material upgrades and dynamic operational optimization. Future research should focus on developing multi-impurity reaction kinetic models, elucidating long-term corrosion product layer evolution, and establishing standardized experimental systems. This review provides crucial theoretical support for establishing impurity control standards and optimizing anti-corrosion strategies for the safe transport of CO₂ in supercritical CCUS pipelines.