Regularities of Change in Thermodynamic Characteristics of the Intermetallic Composition Ln5 Pb3 (Ln–Lanthanides)

Data on the melting temperature and enthalpy, formation enthalpy and heat capacity of intermetallics of the composition Ln5 Pb3 were obtained by a semi-empirical method. A system analysis was carried out and patterns of change in the specified properties of Ln5 Pb3 were established depending on the nature of the entire series of lanthanides. The patterns are complex in nature with the manifestation of the “tetrad effect”. A deviation from the general pattern is observed for the intermetallics of europium and ytterbium, due to their electron structure.

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Published
2025-09-29
DOI
https://doi.org/10.54026/jmms/1127
Primary Topic
Thermodynamic and Structural Properties of Metals and Alloys
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article
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Regularities of Change in Thermodynamic Characteristics of the Intermetallic Composition Ln5 Pb3 (Ln–Lanthanides)

Corby Anderson
Thermodynamic and Structural Properties of Metals and Alloys
article

Regularities of Change in Thermodynamic Characteristics of the Intermetallic Composition Ln5 Pb3 (Ln–Lanthanides)

Corby Anderson
article en

Abstract

Data on the melting temperature and enthalpy, formation enthalpy and heat capacity of intermetallics of the composition Ln5 Pb3 were obtained by a semi-empirical method. A system analysis was carried out and patterns of change in the specified properties of Ln5 Pb3 were established depending on the nature of the entire series of lanthanides. The patterns are complex in nature with the manifestation of the “tetrad effect”. A deviation from the general pattern is observed for the intermetallics of europium and ytterbium, due to their electron structure.

Vol. 6(5)
Colorado School of Mines (US)
Openalex Percentile: Top 70%
Thermodynamic and Structural Properties of Metals and Alloys
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