Design and Evaluation of a Thermally Stable and Salt-Resistant Amphoteric Surfactant-Based Fracturing Fluid for High-Performance Hydraulic Stimulation

As oil and gas exploration advances, the development of deep, low-permeability, high-temperature, and high-salinity reservoirs poses increasing challenges. To address this, a novel amphoteric surfactant (TASS) was synthesized via free radical polymerization, and a high-performance water-based fracturing fluid system was developed. The system exhibited excellent thermal and salt resistance, with viscosity decreasing by less than 3.3% after 72 h at 150 °C and 20 wt% NaCl. It demonstrated clear shear-thinning behavior and strong elasticity. Interfacial activity tests showed that increasing NaCl concentrations reduced interfacial tension from 28.5 to 24.3 mN/m, while the contact angle on sandstone surfaces decreased significantly, indicating enhanced wettability and oil flow. Field applications further confirmed its effectiveness, with oil and gas production increasing by 81% and 133%, respectively, and a payback period of around 10 days. These results highlight the TASS fracturing fluid as a promising solution for stimulation in complex reservoirs. Unlike conventional betaine-type VES, the silane-grafted amphoteric design of TASS ensures viscosity retention at 220 °C and 25 wt% salinity.

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Journal
Polymers
Published
2025-10-14
DOI
https://doi.org/10.3390/polym17202741
Primary Topic
Hydraulic Fracturing and Reservoir Analysis
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article
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article

Design and Evaluation of a Thermally Stable and Salt-Resistant Amphoteric Surfactant-Based Fracturing Fluid for High-Performance Hydraulic Stimulation

Feng Ma, Cao Bao-ge, Lin Li
Polymers
Hydraulic Fracturing and Reservoir Analysis
article

Design and Evaluation of a Thermally Stable and Salt-Resistant Amphoteric Surfactant-Based Fracturing Fluid for High-Performance Hydraulic Stimulation

Feng Ma, Cao Bao-ge, Lin Li
article en

Abstract

As oil and gas exploration advances, the development of deep, low-permeability, high-temperature, and high-salinity reservoirs poses increasing challenges. To address this, a novel amphoteric surfactant (TASS) was synthesized via free radical polymerization, and a high-performance water-based fracturing fluid system was developed. The system exhibited excellent thermal and salt resistance, with viscosity decreasing by less than 3.3% after 72 h at 150 °C and 20 wt% NaCl. It demonstrated clear shear-thinning behavior and strong elasticity. Interfacial activity tests showed that increasing NaCl concentrations reduced interfacial tension from 28.5 to 24.3 mN/m, while the contact angle on sandstone surfaces decreased significantly, indicating enhanced wettability and oil flow. Field applications further confirmed its effectiveness, with oil and gas production increasing by 81% and 133%, respectively, and a payback period of around 10 days. These results highlight the TASS fracturing fluid as a promising solution for stimulation in complex reservoirs. Unlike conventional betaine-type VES, the silane-grafted amphoteric design of TASS ensures viscosity retention at 220 °C and 25 wt% salinity.

PolymersVol. 17(20)
Xi'an Shiyou University (CN), Daqing Oilfield General Hospital (CN), China National Petroleum Corporation (China) (CN)
Openalex Percentile: Top 70%
Hydraulic Fracturing and Reservoir Analysis
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Design and Evaluation of a Thermally Stable and Salt-Resistant Amphoteric Surfactant-Based Fracturing Fluid for High-Performance Hydraulic Stimulation — Feng Ma, Cao Bao-ge, et al. · Polymers (2025) | TGRS Research Map | TGRS