Quantitative Evaluation of Paper Chromatography Spots in Correlation with Physicochemical Properties of Engine Oils

This study explores the potential of paper chromatography for evaluating the condition of used engine oils. A set of 25 oil samples was collected from vehicles operated under real driving conditions and analyzed using both laboratory methods (FTIR spectroscopy, viscosity measurements) and commercial paper test kits. The aim was to quantitatively assess chromatographic spot parameters and investigate their relationships with physicochemical changes in the oil. Refined indicators based on diffusion and contamination zones were proposed and compared with parameters such as oxidation, sulfonation, nitration, and viscosity. The results showed mostly moderate correlations, with only partial consistency between chromatographic and laboratory-derived data. Nevertheless, the analysis highlights that paper chromatography may provide rapid and accessible additional insights for oil condition monitoring, although it cannot substitute standard laboratory testing.

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Publication Details

Journal
Applied Sciences
Published
2025-10-14
DOI
https://doi.org/10.3390/app152011023
Primary Topic
Lubricants and Their Additives
Type
article
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article

Quantitative Evaluation of Paper Chromatography Spots in Correlation with Physicochemical Properties of Engine Oils

Artur Wolak
Applied Sciences
Lubricants and Their Additives
article

Quantitative Evaluation of Paper Chromatography Spots in Correlation with Physicochemical Properties of Engine Oils

Artur Wolak
article en

Abstract

This study explores the potential of paper chromatography for evaluating the condition of used engine oils. A set of 25 oil samples was collected from vehicles operated under real driving conditions and analyzed using both laboratory methods (FTIR spectroscopy, viscosity measurements) and commercial paper test kits. The aim was to quantitatively assess chromatographic spot parameters and investigate their relationships with physicochemical changes in the oil. Refined indicators based on diffusion and contamination zones were proposed and compared with parameters such as oxidation, sulfonation, nitration, and viscosity. The results showed mostly moderate correlations, with only partial consistency between chromatographic and laboratory-derived data. Nevertheless, the analysis highlights that paper chromatography may provide rapid and accessible additional insights for oil condition monitoring, although it cannot substitute standard laboratory testing.

Applied SciencesVol. 15(20)
Krakow University of Economics (PL)
Openalex Percentile: Top 70%
Lubricants and Their Additives
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