Halogen‐Directed Crystallization of Copper(I)‐Based Coordination Polymers for Photocatalytic Oxidative Coupling Reaction of Amines
Halogen‐directed crystallization of Cu(I) coordination polymers ( CCP‐X , X = Cl, Br) enables efficient visible‐light‐driven photocatalytic amine‐to‐imine, in which CCP‐Br exhibits superior photocatalytic performance to CCP‐Cl due to enhanced charge separation and superoxide radical (O 2 •− ) generation, demonstrating a halogen‐modulation strategy for photocatalytic polymer design.
Authors
- Ming‐Hua Chen
- Rong‐Jia Wei (ORCID: https://orcid.org/0000-0001-7898-567X)
- Seongpil An (ORCID: https://orcid.org/0000-0002-4369-5442)
- Qiao‐Ming Deng
- Ri‐Qin Xia (ORCID: https://orcid.org/0000-0003-2962-2113)
- Xu Chen (ORCID: https://orcid.org/0000-0002-2603-102X)
- Tian‐Yu Liu (ORCID: https://orcid.org/0000-0001-6893-326X)
- J.H. Ye
Institutions
- Jinan University (CN)
- Wuhan University (CN)
Publication Details
- Journal
- European Journal of Inorganic Chemistry
- Published
- 2025-10-13
- DOI
- https://doi.org/10.1002/ejic.202500392
- Primary Topic
- Metal-Organic Frameworks: Synthesis and Applications
- Type
- article
- Field-Weighted Citation Impact
- 0.00