Benzoheterocyclic [ <i>b</i> ]-fused BODIPYs: synthesis and effects of N, O, and S on structure, photophysical properties, and aggregation
A one-pot S N Ar/C–H activation gave six heteroatom-[ b ]-fused BODIPYs, clarifying N, O, and S effects on optoelectronic behavior. The dyes show high Φ F , low K nr , and J -aggregation, and follow a new “half-sum rule” for HOMO/LUMO prediction.
Authors
- Wei Jiang (ORCID: https://orcid.org/0000-0003-0083-0322)
- Song Gao (ORCID: https://orcid.org/0000-0002-7759-4404)
- Ling Tian (ORCID: https://orcid.org/0000-0002-6670-3062)
- Yunxia Zhao
- Zhaohui Wang (ORCID: https://orcid.org/0000-0001-5786-5660)
- Yanqing Li (ORCID: https://orcid.org/0000-0003-0575-0399)
- Yanhua Yang (ORCID: https://orcid.org/0000-0003-0482-4552)
- Xiangguang Li (ORCID: https://orcid.org/0000-0001-6443-6215)
- Xiaomao Zhou
- Limin He (ORCID: https://orcid.org/0009-0004-4527-8222)
- Zhang Yongli Zhang
Institutions
- Kunming University (CN)
- University of Chinese Academy of Sciences (CN)
- Tsinghua University (CN)
Publication Details
- Journal
- Organic Chemistry Frontiers
- Published
- 2025-10-13
- DOI
- https://doi.org/10.1039/d5qo01187f
- Citations
- 2
- Primary Topic
- Luminescence and Fluorescent Materials
- Type
- article
- Field-Weighted Citation Impact
- 1.04