Pork-Derived Porous Carbon for Supercapacitors: Achieving “Near-Zero-Loss” and Ultralong Cycle Life
While biomass-derived carbon materials have been extensively explored in the field of energy storage, research focusing on animal protein as a precursor remains relatively scarce, and its potential value is yet to be fully exploited. In this study, oxygen-rich protein-based biomass porous carbons were prepared using pork as the raw material and phosphate distarch as the additive via a strategy involving compositing, subsequent carbonization, and KOH activation. Among these carbons, sample APE-2 possessed a high oxygen content of 9.81%, a hierarchical micromesoporous structure dominated by micropores, specific surface area (SSA) per unit amount of 1599 m<sup>2</sup> g<sup>-1</sup>, and pore volume at 0.692 cm<sup>3</sup> g<sup>-1</sup>. Under a three-electrode cell where 6 M KOH functions as the electrolyte, it demonstrated an excellent reversible specific capacitance of 565 F g<sup>-1</sup> under 1 A g<sup>-1</sup> as well as outstanding rate capability, maintaining a specific capacitance of 474 F g<sup>-1</sup> even at 35 A g<sup>-1</sup>. When utilized as electrode materials to assemble symmetric supercapacitors (SCs) using 6 M KOH, it achieved a prominent reversible specific capacitive performance at 250 F g<sup>-1</sup> under 0.5 A g<sup>-1</sup> as well as remained at 143 F g<sup>-1</sup> under 20 A g<sup>-1</sup>. It also exhibits an ultrastable cycling behavior with nearly "zero decay" as evidenced by a capacitance retention of 99.7% after 20,000 cycles.
Authors
- Yulei Liu
- Han Zhang (ORCID: https://orcid.org/0000-0003-2016-4179)
- Han Peng
- Ziwen Wang (ORCID: https://orcid.org/0000-0002-6872-5484)
- Minjie Wang (ORCID: https://orcid.org/0000-0001-8195-5295)
- Huihua Li (ORCID: https://orcid.org/0000-0002-4272-4248)
Institutions
- Central South University (CN)
- Pingdingshan University (CN)
- Zhengzhou University (CN)
- College of Tourism (BG)
- Beijing University of Chemical Technology (CN)
Publication Details
- Journal
- ACS Omega
- Published
- 2025-10-13
- DOI
- https://doi.org/10.1021/acsomega.5c08616
- Citations
- 2
- Primary Topic
- Supercapacitor Materials and Fabrication
- Type
- article
- Field-Weighted Citation Impact
- 0.85