Giant Nonreciprocal Band Structure Effect in a Multiferroic Material

Multiferroic materials, combining ferroelectricity and ferromagnetism, can host complex band phenomena. Using density functional theory and symmetry analysis, we identify the multiferroic EuO as a prototypical system exhibiting a giant, switchable nonreciprocal band structure effect, that is an asymmetry in electronic bands at special points in the Brillouin zone, enabled by spin-orbit coupling. In particular, our results highlight the crucial role of magnetic symmetries---beyond inversion and time-reversal breaking. Ultimately, the predicted effect leads to a colossal bulk photovoltaic response, with injection currents far exceeding those in known oxides, enabling new cross-functionalities.

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Publication Details

Journal
Physical Review Letters
Published
2025-11-14
DOI
https://doi.org/10.1103/15ws-ftbf
Citations
1
Primary Topic
Material Science and Thermodynamics
Type
article
Field-Weighted Citation Impact
0.71
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Giant Nonreciprocal Band Structure Effect in a Multiferroic Material

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Giant Nonreciprocal Band Structure Effect in a Multiferroic Material

Srdjan Stavrić, Álvaro R. Puente-Uriona, Julen Ibañez-Azpiroz, Silvia Picozzi, Paolo Barone, Baishun Yang, Giuseppe Cuono, Andrea Droghetti
article en
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Abstract

Multiferroic materials, combining ferroelectricity and ferromagnetism, can host complex band phenomena. Using density functional theory and symmetry analysis, we identify the multiferroic EuO as a prototypical system exhibiting a giant, switchable nonreciprocal band structure effect, that is an asymmetry in electronic bands at special points in the Brillouin zone, enabled by spin-orbit coupling. In particular, our results highlight the crucial role of magnetic symmetries---beyond inversion and time-reversal breaking. Ultimately, the predicted effect leads to a colossal bulk photovoltaic response, with injection currents far exceeding those in known oxides, enabling new cross-functionalities.

Physical Review LettersVol. 135(20)
Ca' Foscari University of Venice (IT), University of Belgrade (RS), Material Physics Center (ES), Institute of Economic Sciences (RS), Consorzio Roma Ricerche (IT), Donostia International Physics Center (ES), University of Milano-Bicocca (IT)
Openalex Percentile: Top 26%
Material Science and Thermodynamics
0.71
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