Activation of N-containing olefins and alkynes with superacids
In superacid conditions, through the capacity to generate polycationic species from functionalized organic substrates, original reactions can be conducted from unsaturated nitrogen-containing compounds, ranging from hydro- and heterofluorination to polycyclization. These strategies allow the synthesis of elaborate enantioenriched polyfunctionalized compounds, and their final exploitation in a late-stage modification approach also demonstrates their synthetic potential.
Authors
- Hélène Carreyre
- Bastien Michelet (ORCID: https://orcid.org/0000-0002-3248-5781)
- Sébastien Thibaudeau (ORCID: https://orcid.org/0000-0002-6246-5829)
- Agnès Martin‐Mingot (ORCID: https://orcid.org/0000-0002-2633-3714)
- Delphine Pichon (ORCID: https://orcid.org/0000-0002-2307-6388)
- Frédéric Lecornué
Institutions
- Centre National de la Recherche Scientifique (FR)
- Université de Poitiers (FR)
Publication Details
- Journal
- Comptes Rendus Chimie
- Published
- 2025-08-29
- DOI
- https://doi.org/10.5802/crchim.416
- Primary Topic
- Organic and Inorganic Chemical Reactions
- Type
- article
- Field-Weighted Citation Impact
- 0.00