The core–shell structure improving the third-order nonlinear optical response of Zintl ions: M@Sn <sub>9</sub> <sup>4−</sup>
Core–shell M@Sn 9 4− clusters boost the third-order NLO response through promoted electron transfer and 3D aromaticity, with Pd@Sn 9 4− exhibiting an order-of-magnitude superior performance compared to Sn 9 4− .
Authors
- Qiaohong Li (ORCID: https://orcid.org/0000-0001-9286-3580)
- Yayu Yan
- Jiali Chen (ORCID: https://orcid.org/0000-0003-3150-8854)
- Jian Zhang (ORCID: https://orcid.org/0000-0002-0428-7294)
- Z. Wang (ORCID: https://orcid.org/0000-0002-0928-2070)
- Xiaolan Zheng
- Wanting Xia
Institutions
- Chinese Academy of Sciences (CN)
- Fujian Institute of Research on the Structure of Matter (CN)
- University of Chinese Academy of Sciences (CN)
- Fuzhou University (CN)
Publication Details
- Journal
- Materials Advances
- Published
- 2025-01-01
- DOI
- https://doi.org/10.1039/d5ma00992h
- Primary Topic
- Nonlinear Optical Materials Research
- Type
- article
- Field-Weighted Citation Impact
- 0.00
Funders
- National Natural Science Foundation of China