Isomeric double-cavity coordination cages: to encapsulate or not to encapsulate the guest
A series of three isomeric double-cavity discrete coordination cages with Pd<sub>3</sub>L<sub>4</sub> formulation, constructed from Pd(II) and regioisomeric tris-monodentate ligands, are compared for binding pyrazine <i>N</i>,<i>N</i>'-dioxide. Two of the isomeric cages efficiently encapsulated the guest in both cavities, whereas one of the isomers rejected the guest completely.
Authors
- Dillip Kumar Chand (ORCID: https://orcid.org/0000-0003-1115-0138)
- Shobhana Krishnaswamy (ORCID: https://orcid.org/0000-0003-2479-2826)
- Ashish Kumar (ORCID: https://orcid.org/0000-0003-4249-0055)
Institutions
- Indian Institute of Technology Madras (IN)
Publication Details
- Journal
- Dalton Transactions
- Published
- 2025-01-01
- DOI
- https://doi.org/10.1039/d5dt02147b
- Citations
- 1
- Primary Topic
- Magnetism in coordination complexes
- Type
- article
- Field-Weighted Citation Impact
- 0.43