Variational quantum simulation of time-local quantum master equations via quantum jump

Strong coupling and environmental memory render many open quantum systems intractable to classical computation. To overcome this barrier, we present a variational quantum algorithm capable of solving generalized form time-local quantum master equations directly on noisy intermediate-scale quantum (NISQ) processors. Our approach combines four key innovations: (1) a pair-vector stochastic Schrödinger equation to unravel time-local quantum master equations, (2) deterministic evolution projected onto parameterized circuits via McLachlan's principle and stochastic jump implementation via singular-value decomposition, (3) using Hadamard tests circuits to measure the jump rates and the element of reduced density matrices, and (4) using no-evolution sampling to sample trajectories. The resulting protocol remains resilient under realistic hardware noise. We validate it on both classical simulators and a 66-qubit superconducting processor for solving the Redfield master equation and fourth-order time-local non-Markovian master equation and find that it can successfully capture key features of complex open quantum dynamics-including non-Markovian oscillations and strong-coupling effects. Our approach establishes a practical pathway toward scalable simulations of open quantum systems in the NISQ era.

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Publication Details

Journal
The Journal of Chemical Physics
Published
2025-10-09
DOI
https://doi.org/10.1063/5.0291793
Citations
1
Primary Topic
Quantum Computing Algorithms and Architecture
Type
article
Field-Weighted Citation Impact
2.48
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article

Variational quantum simulation of time-local quantum master equations via quantum jump

WanZhen Liang, Zhihao Lan, Jie Liu, Zhenyu Li
1 citations
The Journal of Chemical Physics
Quantum Computing Algorithms and Architecture
2.48
article

Variational quantum simulation of time-local quantum master equations via quantum jump

WanZhen Liang, Zhihao Lan, Jie Liu, Zhenyu Li
article en
1 citations

Abstract

Strong coupling and environmental memory render many open quantum systems intractable to classical computation. To overcome this barrier, we present a variational quantum algorithm capable of solving generalized form time-local quantum master equations directly on noisy intermediate-scale quantum (NISQ) processors. Our approach combines four key innovations: (1) a pair-vector stochastic Schrödinger equation to unravel time-local quantum master equations, (2) deterministic evolution projected onto parameterized circuits via McLachlan's principle and stochastic jump implementation via singular-value decomposition, (3) using Hadamard tests circuits to measure the jump rates and the element of reduced density matrices, and (4) using no-evolution sampling to sample trajectories. The resulting protocol remains resilient under realistic hardware noise. We validate it on both classical simulators and a 66-qubit superconducting processor for solving the Redfield master equation and fourth-order time-local non-Markovian master equation and find that it can successfully capture key features of complex open quantum dynamics-including non-Markovian oscillations and strong-coupling effects. Our approach establishes a practical pathway toward scalable simulations of open quantum systems in the NISQ era.

The Journal of Chemical PhysicsVol. 163(14)
University of Science and Technology of China (CN), Xiamen University (CN)
Openalex Percentile: Top 8%
Quantum Computing Algorithms and Architecture
2.48
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