Mesoscopic Liquids Emit Thermal Waves Under Shear Strain or Microflow

Liquids like water are not expected to produce a thermal change under shear strain or flow (away from extreme conditions). In this study, we reveal experimental conditions for which the conventional athermal hydrodynamic assumption is no longer valid. We highlight the establishment of non-equilibrium hot and cold thermal states occurring when a mesoscopic confined liquid is set in motion. Two stress situations are considered: low-frequency shear stress at large strain amplitude and microfluidic transport (pressure gradient). Two liquids are tested: water and glycerol at room temperature. In confined conditions (submillimeter scale), these liquids exhibit stress-induced thermal waves. We interpret the emergence of non-equilibrium temperatures as a consequence of the solicitation of the mesoscopic liquid elasticity. In analogy with elastic deformation, the mesoscopic volume decreases or increases slightly, which leads to a change in temperature (thermo-mechanical energy conversion). The energy acquired or released is converted to heat or cold, respectively. To account for these non-equilibrium temperatures, the mesoscopic flow is no longer considered as a complete dissipative process but as a way of propagating shear and thus compressive waves. This conclusion is consistent with recent theoretical developments showing that liquids propagate shear elastic waves at small scales.