Solubility of 4,7-dioxo-7-(4-methylphenyl)heptanoic acid in some organic solvents

The temperature dependences of the solubility of 4,7-dioxo-7-(4-methylphenyl)heptanoic acid in organic solvents, namely methyl acetate, ethyl acetate, acetonitrile, acetone, n-propanol, iso-propanol, n-butanol and iso-butanol, were studied and the thermodynamic parameters of solubility were calculated. The enthalpy and entropy of melting of the acid under study were determined by differential thermal analysis. The thermodynamic parameters were recalculated to the generally accepted temperature of 298.15 K. The enthalpies and entropies of mixing of the components at 298.15 K were calculated. Keywords: solubility, enthalpy of dissolution, enthalpy of mixing, enthalpy of melting, 4,7-dioxo-7-(4-methylphenyl)heptanoic acid.

Authors

Publication Details

Journal
Visnyk of the Lviv University Series Chemistry
Published
2025-01-01
DOI
https://doi.org/10.30970/vch.6601.232
Primary Topic
Analytical Chemistry and Chromatography
Type
article
Field-Weighted Citation Impact
0.00

Funders

Controls
|||
ALL TIME
JAN
FEB
MAR
APR
MAY
JUN
JUL
AUG
SEP
OCT
article

Solubility of 4,7-dioxo-7-(4-methylphenyl)heptanoic acid in some organic solvents

Yuriy I. Horak, I.B. Sobechko, N.I. Tischenko, M. Ohorodnik
Visnyk of the Lviv University Series Chemistry
Analytical Chemistry and Chromatography
article

Solubility of 4,7-dioxo-7-(4-methylphenyl)heptanoic acid in some organic solvents

Yuriy I. Horak, I.B. Sobechko, N.I. Tischenko, M. Ohorodnik
article en

Abstract

The temperature dependences of the solubility of 4,7-dioxo-7-(4-methylphenyl)heptanoic acid in organic solvents, namely methyl acetate, ethyl acetate, acetonitrile, acetone, n-propanol, iso-propanol, n-butanol and iso-butanol, were studied and the thermodynamic parameters of solubility were calculated. The enthalpy and entropy of melting of the acid under study were determined by differential thermal analysis. The thermodynamic parameters were recalculated to the generally accepted temperature of 298.15 K. The enthalpies and entropies of mixing of the components at 298.15 K were calculated. Keywords: solubility, enthalpy of dissolution, enthalpy of mixing, enthalpy of melting, 4,7-dioxo-7-(4-methylphenyl)heptanoic acid.

Visnyk of the Lviv University Series ChemistryVol. 66(1)
Science Foundation Ireland, Ministry of Education and Science of Ukraine
Openalex Percentile: Top 74%
Analytical Chemistry and Chromatography
AI Navigator

Ask Laika to Summarize, Analyze, and Connect papers live on the map.

Summarize Papers & Methodologies

Extract key findings, datasets, and comparative methods across publications.

Benchmark Rankings & Visual Analytics

Rank top research institutions, authors, funders, topics, and journals by Field-Weighted Citation Impact (FWCI) and paper volume with instant charts.

Connect Distant Disciplines

Bridge topological clusters on the map to find hidden collaborative intersections.