Rapid and living polymerization of renewable methylene butyrolactones <i>via</i> borane/phosphine Lewis pairs

This study presents a highly effective organic Lewis pair system, combining tris(pentafluorophenyl)borane (B(C 6 F 5 ) 3 ) with the strong organophosphorus superbase P(NI i Pr)Ph 2 , enabling rapid and living polymerization of renewable methylene butyrolactones.

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Publication Details

Journal
Polymer Chemistry
Published
2025-01-01
DOI
https://doi.org/10.1039/d5py00789e
Primary Topic
Organoboron and organosilicon chemistry
Type
article
Field-Weighted Citation Impact
0.00
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article

Rapid and living polymerization of renewable methylene butyrolactones via borane/phosphine Lewis pairs

Lieqiang Liao, Yun Bai, Yuetao Zhang, Shuang Liu et al.
Polymer Chemistry
Organoboron and organosilicon chemistry
article

Rapid and living polymerization of renewable methylene butyrolactones via borane/phosphine Lewis pairs

Lieqiang Liao, Yun Bai, Yuetao Zhang, Shuang Liu, Jianghua He, Yibao Li
article en

Abstract

This study presents a highly effective organic Lewis pair system, combining tris(pentafluorophenyl)borane (B(C 6 F 5 ) 3 ) with the strong organophosphorus superbase P(NI i Pr)Ph 2 , enabling rapid and living polymerization of renewable methylene butyrolactones.

Polymer ChemistryVol. 16(44)
Jilin University (CN), Gannan Normal University (CN)
Openalex Percentile: Top 79%
Organoboron and organosilicon chemistry
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