Catalytic olefin hydrosilylation with an original bis(iminophosphorane)phosphine NPN Co <sup>II</sup> complex
An original bis(iminophosphorane)phosphine NPN ligand was synthesised and coordinated to Co<sup>II</sup>. Both the ligand and the complex were characterised by multinuclear NMR spectroscopy and X-ray crystallography. The Co<sup>II</sup> complex (1.5 mol%) in the presence of NaOMe (3 mol%) catalyses the hydrosilylation of olefins within a few hours at 60 °C. Both 1-alkenes and less reactive internal ones built upon a norbornene skeleton were efficiently transformed.
Authors
- Sophie Bourcier (ORCID: https://orcid.org/0000-0001-6914-3956)
- Audrey Auffrant (ORCID: https://orcid.org/0000-0001-6952-4775)
- Ingrid Popovici
- Yu‐Jia Chen (ORCID: https://orcid.org/0000-0001-7563-4073)
- Nicolas Casaretto (ORCID: https://orcid.org/0000-0003-0636-983X)
Institutions
- Centre National de la Recherche Scientifique (FR)
- École Polytechnique (FR)
- Laboratoire de Chimie Moléculaire (FR)
Publication Details
- Journal
- Dalton Transactions
- Published
- 2025-01-01
- DOI
- https://doi.org/10.1039/d5dt02099a
- Citations
- 1
- Primary Topic
- Organometallic Complex Synthesis and Catalysis
- Type
- article
- Field-Weighted Citation Impact
- 0.94