Slow magnetic relaxation in a trinuclear spin-crossover Co( <scp>ii</scp> ) compound with metal–metal bonding
This study investigates the molecular spin-qubit properties of a rigid trinuclear cobalt complex, presenting the first example of spin-crossover in a compound with metal-metal bonds. Pulsed electron paramagnetic resonance spectroscopy provides deeper insight into the spin-qubit behaviour, including the spin-lattice and spin-spin relaxation times.
Authors
- Shie‐Ming Peng (ORCID: https://orcid.org/0000-0003-1412-5018)
- Yoshihiro Sekine (ORCID: https://orcid.org/0000-0001-9513-392X)
- Kil Sik Min (ORCID: https://orcid.org/0000-0001-8777-2174)
- Shinya Hayami (ORCID: https://orcid.org/0000-0001-8392-2382)
- Jeongcheol Shin (ORCID: https://orcid.org/0000-0001-9589-5318)
- Hitome Kobayashi (ORCID: https://orcid.org/0000-0002-4057-4514)
- Sun Hee Kim (ORCID: https://orcid.org/0000-0001-6557-1996)
- Ming‐Chuan Cheng (ORCID: https://orcid.org/0000-0003-2094-3981)
- Hikaru Zenno
Institutions
- National Taiwan University (TW)
- Kyungpook National University (KR)
- Korea Basic Science Institute (KR)
- Kumamoto Industrial Research Institute (JP)
- Duksung Women's University (KR)
- Chung-Ang University (KR)
- Kumamoto University (JP)
Publication Details
- Journal
- Chemical Communications
- Published
- 2025-01-01
- DOI
- https://doi.org/10.1039/d5cc03879k
- Primary Topic
- Magnetism in coordination complexes
- Type
- article
- Field-Weighted Citation Impact
- 0.00