Linkage-dependent nano-conductivity of free-standing covalent organic membranes

Free-standing covalent organic membranes (COMs) with β-ketoenamine (TAPA-Tp), imine (TAPA-DTP), and vinylene (NTB-PDAN) linkages were interfacially fabricated, and their linkage-dependent nano-conductivity was probed using conductive atomic force microscopy (CAFM). The COMs exhibited excellent electrical continuity, with NTB-PDAN (15.78 pA) demonstrating superior nano-conductivity over TAPA-DTP (0.56 pA) and TAPA-Tp (0.42 pA).

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Publication Details

Journal
Chemical Communications
Published
2025-01-01
DOI
https://doi.org/10.1039/d5cc04346h
Primary Topic
Fuel Cells and Related Materials
Type
article
Field-Weighted Citation Impact
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article

Linkage-dependent nano-conductivity of free-standing covalent organic membranes

Bishnu P. Biswal, Adithyan Puthukkudi, Biplab K. Patra, S. S. Rout et al.
Chemical Communications
Fuel Cells and Related Materials
article

Linkage-dependent nano-conductivity of free-standing covalent organic membranes

Bishnu P. Biswal, Adithyan Puthukkudi, Biplab K. Patra, S. S. Rout, Amjath Nihal Thiruthimmal, Om Prakash Swain
article en

Abstract

Free-standing covalent organic membranes (COMs) with β-ketoenamine (TAPA-Tp), imine (TAPA-DTP), and vinylene (NTB-PDAN) linkages were interfacially fabricated, and their linkage-dependent nano-conductivity was probed using conductive atomic force microscopy (CAFM). The COMs exhibited excellent electrical continuity, with NTB-PDAN (15.78 pA) demonstrating superior nano-conductivity over TAPA-DTP (0.56 pA) and TAPA-Tp (0.42 pA).

Chemical CommunicationsVol. 61(87)
National Institute of Science Education and Research (IN), Homi Bhabha National Institute (IN), Institute of Minerals and Materials Technology (IN), Academy of Scientific and Innovative Research (IN)
Openalex Percentile: Top 73%
Fuel Cells and Related Materials
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