Hydrolytic and oxidative stability of precursors for the synthesis of sulfide solid electrolytes

The oxidative and hydrolytic stability of the precursors Li2S and P2S5 for the synthesis of sulfide solid electrolytes was studied using gravimetric analysis. The study was conducted in air with different water content and dry argon. It was established that the water content in air significantly affects the stability of materials. Li2S and P2S5 are unstable even in air with the water content of 5 ppm. Moreover, it was found that the oxidative-hydrolytic stability of Li2S depends on the presence of impurities.

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Publication Details

Journal
Electrochemical Energetics
Published
2025-09-23
DOI
https://doi.org/10.18500/1608-4039-2025-25-3-115-123
Primary Topic
Chemical Looping and Thermochemical Processes
Type
article
Field-Weighted Citation Impact
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article

Hydrolytic and oxidative stability of precursors for the synthesis of sulfide solid electrolytes

Elena Kuzmina, В. С. Колосницын, Yulia A. Pilyugina
Electrochemical Energetics
Chemical Looping and Thermochemical Processes
article

Hydrolytic and oxidative stability of precursors for the synthesis of sulfide solid electrolytes

Elena Kuzmina, В. С. Колосницын, Yulia A. Pilyugina
article en

Abstract

The oxidative and hydrolytic stability of the precursors Li2S and P2S5 for the synthesis of sulfide solid electrolytes was studied using gravimetric analysis. The study was conducted in air with different water content and dry argon. It was established that the water content in air significantly affects the stability of materials. Li2S and P2S5 are unstable even in air with the water content of 5 ppm. Moreover, it was found that the oxidative-hydrolytic stability of Li2S depends on the presence of impurities.

Electrochemical EnergeticsVol. 25(3)
Openalex Percentile: Top 73%
Chemical Looping and Thermochemical Processes
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