Effect of additive modifiers on the combustion characteristics of composite aluminized propellants

We studied the effect of modifier additives TiB2, AlMgB14, (NH4)2TiF6, NH4BF4, Ca3(PO4)2 on the combustion parameters of composite propellants based on aluminum powder as a fuel (about 20% wt.), ammonium perchlorate as an oxidizer (about 60% wt.), and energetic binder (MPVT about 20% wt.). Additives were introduced in an amount of about 2%. The burning rates of propellants were measured and condensed combustion products were studied at a pressure of 0.35 MPa. The effect of additives was assessed using the following parameters: increasing the burning rate, reducing combustion incompleteness, mass and size of agglomerates. The most effective additives were NH4BF4 and TiB2. Conclusions are drawn about the prospects of using the studied additives to obtain the required combustion parameters.

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Publication Details

Journal
Химическая физика / Advances in Chemical Physics
Published
2025-01-01
DOI
https://doi.org/10.7868/s3034612625010073
Primary Topic
Energetic Materials and Combustion
Type
article
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article

Effect of additive modifiers on the combustion characteristics of composite aluminized propellants

О. Г. Глотов
Химическая физика / Advances in Chemical Physics
Energetic Materials and Combustion
article

Effect of additive modifiers on the combustion characteristics of composite aluminized propellants

О. Г. Глотов
article en

Abstract

We studied the effect of modifier additives TiB2, AlMgB14, (NH4)2TiF6, NH4BF4, Ca3(PO4)2 on the combustion parameters of composite propellants based on aluminum powder as a fuel (about 20% wt.), ammonium perchlorate as an oxidizer (about 60% wt.), and energetic binder (MPVT about 20% wt.). Additives were introduced in an amount of about 2%. The burning rates of propellants were measured and condensed combustion products were studied at a pressure of 0.35 MPa. The effect of additives was assessed using the following parameters: increasing the burning rate, reducing combustion incompleteness, mass and size of agglomerates. The most effective additives were NH4BF4 and TiB2. Conclusions are drawn about the prospects of using the studied additives to obtain the required combustion parameters.

Химическая физика / Advances in Chemical PhysicsVol. 44(1)
Openalex Percentile: Top 68%
Energetic Materials and Combustion
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