A low-potential lithium-biphenyl anolyte for high-performance nonaqueous redox flow batteries with a metal–organic-framework-based separator

A Li-biphenyl (BP) anolyte is adopted in a 2.7 V Li-BP-LiI<sub>3</sub> nonaqueous redox flow battery (NRFB). The Fe-N-C MOF separator mitigates cross-contamination and enhances LiI<sub>3</sub> reduction, as confirmed by DFT. The NRFB exhibits 80 Ah L<sup>-1</sup> capacity and 96% retention over 100 cycles, offering a pathway for achieving high-voltage and high-stability.

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Publication Details

Journal
Chemical Communications
Published
2025-01-01
DOI
https://doi.org/10.1039/d5cc04436g
Primary Topic
Advanced battery technologies research
Type
article
Field-Weighted Citation Impact
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article

A low-potential lithium-biphenyl anolyte for high-performance nonaqueous redox flow batteries with a metal–organic-framework-based separator

Hongning Chen, Junpeng Li, Changyong Shao, Yu Liu
Chemical Communications
Advanced battery technologies research
article

A low-potential lithium-biphenyl anolyte for high-performance nonaqueous redox flow batteries with a metal–organic-framework-based separator

Hongning Chen, Junpeng Li, Changyong Shao, Yu Liu
article en

Abstract

A Li-biphenyl (BP) anolyte is adopted in a 2.7 V Li-BP-LiI<sub>3</sub> nonaqueous redox flow battery (NRFB). The Fe-N-C MOF separator mitigates cross-contamination and enhances LiI<sub>3</sub> reduction, as confirmed by DFT. The NRFB exhibits 80 Ah L<sup>-1</sup> capacity and 96% retention over 100 cycles, offering a pathway for achieving high-voltage and high-stability.

Chemical CommunicationsVol. 61(89)
Shenzhen University (CN), Shenzhen Technology University (CN)
Openalex Percentile: Top 73%
Advanced battery technologies research
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