From polyanions to infinite chains: chemical bonding evolution in AX <sub>3</sub> polyhalides under pressure
CsI 3 : pressure-induced change from electron-rich multicenter bonds (ERMBs) in finite linear I 3 − units towards electron-deficient multicenter bonds (EDMBs) in infinite linear iodine chains, I ∞ , explains the properties of infinite linear halide chains.
Authors
- P. Rodríguez‐Hernández (ORCID: https://orcid.org/0000-0002-4148-6516)
- Álvaro Lobato (ORCID: https://orcid.org/0000-0002-2798-6178)
- Hussien H. Osman (ORCID: https://orcid.org/0000-0003-1411-8299)
- F. J. Manjón (ORCID: https://orcid.org/0000-0002-3926-1705)
- Enrico Bandiello (ORCID: https://orcid.org/0000-0003-0956-3195)
- Alfonso Muñoz (ORCID: https://orcid.org/0000-0003-3347-6518)
- Fernando Izquierdo‐Ruiz (ORCID: https://orcid.org/0000-0001-7237-4720)
Institutions
- Universidad Complutense de Madrid (ES)
- Universidad de La Laguna (ES)
- Universitat de València (ES)
- Universitat Politècnica de València (ES)
- Helwan University (EG)
Publication Details
- Journal
- Journal of Materials Chemistry C
- Published
- 2025-01-01
- DOI
- https://doi.org/10.1039/d5tc01566a
- Citations
- 2
- Primary Topic
- Crystallography and molecular interactions
- Type
- article
- Field-Weighted Citation Impact
- 3.51
Funders
- European Commission
- Generalitat Valenciana
- Agencia Estatal de Investigación