5-Imino-5λ<sup>4</sup>-heptathiepane 3-oxide. More exuberent anomeric effects.

The two previous  posts, on the topic of anomeric effects in 7-membered sulfur rings illustrated how orbital interactions between the lone pairs in the molecules and S-S bonds produced widely varying S-S bond lengths in the molecules, some are shorter than normal (which is ~2.05Å for e.g. the S8 ring) by ~ 0.1Å and some […]

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Publication Details

Journal
Front Matter
Published
2025-05-20
DOI
https://doi.org/10.59350/fyyc9-6hz32
Primary Topic
Chemical Reaction Mechanisms
Type
article
Field-Weighted Citation Impact
0.00
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article

5-Imino-5λ4-heptathiepane 3-oxide. More exuberent anomeric effects.

Henry S. Rzepa
Front Matter
Chemical Reaction Mechanisms
article

5-Imino-5λ4-heptathiepane 3-oxide. More exuberent anomeric effects.

Henry S. Rzepa
article en

Abstract

The two previous  posts, on the topic of anomeric effects in 7-membered sulfur rings illustrated how orbital interactions between the lone pairs in the molecules and S-S bonds produced widely varying S-S bond lengths in the molecules, some are shorter than normal (which is ~2.05Å for e.g. the S8 ring) by ~ 0.1Å and some […]

Front Matter
Openalex Percentile: Top 79%
Chemical Reaction Mechanisms
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5-Imino-5λ<sup>4</sup>-heptathiepane 3-oxide. More exuberent anomeric effects. — Henry S. Rzepa · Front Matter (2025) | TGRS Research Map | TGRS