<i>Operando</i> fluorescence lifetime imaging microscopy during Li <sup>+</sup> intercalation into graphitic electrodes

The evolution of emission background within Li-ion half-cells was monitored using <i>operando</i> fluorescence lifetime imaging microscopy. Fluorescence lifetimes were spatially mapped on graphite electrodes during lithiation and delithiation within two electrolyte formulations containing either a Li[PF<sub>6</sub>] or Li[ClO<sub>4</sub>] salt, which highlighted differing emission characteristics associated with salt stability.

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Publication Details

Journal
Chemical Communications
Published
2025-01-01
DOI
https://doi.org/10.1039/d5cc04045k
Primary Topic
Chemistry and Stereochemistry Studies
Type
article
Field-Weighted Citation Impact
0.00

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article

Operando fluorescence lifetime imaging microscopy during Li + intercalation into graphitic electrodes

Alex R. Neale, Laurence J. Hardwick, Stanley W. Botchway, Matthew Quarrell et al.
Chemical Communications
Chemistry and Stereochemistry Studies
article

Operando fluorescence lifetime imaging microscopy during Li + intercalation into graphitic electrodes

Alex R. Neale, Laurence J. Hardwick, Stanley W. Botchway, Matthew Quarrell, Thukshan Samarakoon, Oliver J. Barker
article en

Abstract

The evolution of emission background within Li-ion half-cells was monitored using <i>operando</i> fluorescence lifetime imaging microscopy. Fluorescence lifetimes were spatially mapped on graphite electrodes during lithiation and delithiation within two electrolyte formulations containing either a Li[PF<sub>6</sub>] or Li[ClO<sub>4</sub>] salt, which highlighted differing emission characteristics associated with salt stability.

Chemical CommunicationsVol. 61(86)
University of Liverpool (GB), Research Complex at Harwell (GB), The Faraday Institution (GB)
Science and Technology Facilities Council
Openalex Percentile: Top 79%
Chemistry and Stereochemistry Studies
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<i>Operando</i> fluorescence lifetime imaging microscopy during Li <sup>+</sup> intercalation into graphitic electrodes — Alex R. Neale, Laurence J. Hardwick, et al. · Chemical Communications (2025) | TGRS Research Map | TGRS