3D printing of alumina components via Fused Granulate Fabrication technology and solvent-free debinding of highly filled feedstocks comprising (LD)-polyethylene and cellulose

This study focuses on the development of components in gyroid structure based on alumina as integral part of the novel burner designed for the non-premixed combustion of ammonia. During application, the component has to withstand repeated thermal shocks of approx. 600 K or more. Due to the high geometric complexity of the gyroid structure and the need for lightweight design with both macroporous regions and microporous features only the 3D printing was suitable as manufacturing technology; in the present work Fused Granulate Fabrication was used. The manufacturing routine for the employed granules with special regard to the binder system is developed. A customized thermal debinding regime without wick or solvent debinding is presented. Challenges such as the formation of bubbles and the swelling of the samples during thermal debinding were met by adjusting the printing parameters to create porosity and cavities between the deposited strands during 3D printing. Sintered bars fabricated using optimized printing parameters had a shrinkage of 13 %, an open porosity of 41 % and a flexural strength of 50 MPa, respectively. These values are sufficient for the application of the components in the novel burners. As last part of this work sheet-gyroid structures were prepared using a 1.0 mm and 0.4 mm nozzles. These structures successfully survived 5 thermal shock cycles, each involving heating to 1100 °C followed by air quenching, which is an excellent result in terms of thermal shock performance.