Synthesis of Sulfondiimidoates by Desoxychlorination of Sulfonimidamides
A synthetic procedure toward sulfondiimidoates, the aza-oxo inverse sulfonamides, was developed. The sulfondiimidoates reported here were synthesized by desoxychlorination of sulfonimidamides. The <i>in situ</i> generated sulfondiimidoyl chlorides were transformed into the desired sulfondiimidoates by alcoholysis. The method presented allows for redox-neutral access to sulfondiimidoates.
Authors
- Christian D. Lorenz (ORCID: https://orcid.org/0000-0003-1028-4804)
- Michael Reggelin (ORCID: https://orcid.org/0000-0003-3650-3921)
- Erik Friedrich (ORCID: https://orcid.org/0000-0002-7175-2221)
- Timo Heinrich (ORCID: https://orcid.org/0000-0001-9120-8410)
- Dorian Didier (ORCID: https://orcid.org/0000-0002-6358-1485)
- Philip Freund
Institutions
- Technische Universität Darmstadt (DE)
Publication Details
- Journal
- Organic Letters
- Published
- 2025-10-03
- DOI
- https://doi.org/10.1021/acs.orglett.5c03831
- Citations
- 2
- Primary Topic
- Synthesis and Catalytic Reactions
- Type
- article
- Field-Weighted Citation Impact
- 1.87