The direct photochemical cross-esterification of alcohols <i>via</i> site-selective C–H bromination

We have developed a direct photochemical cross-esterification of alcohols that proceeds <i>via</i> the <i>in situ</i> generation of acyl bromides. The C-H bond of a benzyl alcohol is selectively activated by a bromo source under light irradiation, enabling the cross-esterification to afford a variety of functionalized esters.

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Publication Details

Journal
Chemical Communications
Published
2025-01-01
DOI
https://doi.org/10.1039/d5cc03371c
Citations
1
Primary Topic
Oxidative Organic Chemistry Reactions
Type
article
Field-Weighted Citation Impact
0.94
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article

The direct photochemical cross-esterification of alcohols via site-selective C–H bromination

Hiroyoshi Takamura, Isao Kadota, Kenta Tanaka, Akari Miyamoto
1 citations
Chemical Communications
Oxidative Organic Chemistry Reactions
0.94
article

The direct photochemical cross-esterification of alcohols via site-selective C–H bromination

Hiroyoshi Takamura, Isao Kadota, Kenta Tanaka, Akari Miyamoto
article en
1 citations

Abstract

We have developed a direct photochemical cross-esterification of alcohols that proceeds <i>via</i> the <i>in situ</i> generation of acyl bromides. The C-H bond of a benzyl alcohol is selectively activated by a bromo source under light irradiation, enabling the cross-esterification to afford a variety of functionalized esters.

Chemical CommunicationsVol. 61(89)
Okayama University (JP)
Openalex Percentile: Top 21%
Oxidative Organic Chemistry Reactions
0.94
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