2-Fluorobenzyl ( <i>Z</i> )-2-(5-chloro-2-oxoindolin-3-ylidene)hydrazine-1-carbodithioate dimethyl sulfoxide monosolvate
In the title solvate, C<sub>16</sub>H<sub>11</sub>ClFN<sub>3</sub>OS<sub>2</sub>·C<sub>2</sub>H<sub>6</sub>OS, the C=N bond adopts a <i>Z</i>-configuration facilitating the formation of an intra-molecular N-H⋯O hydrogen bond to the carbonyl O atom in an <i>S</i>(6) loop. The di-methyl-sulfoxide solvent mol-ecule accepts a strong discrete N-H⋯O hydrogen bond from the γ-lactam grouping. In the extended structure, C<sub>ar</sub>-H⋯S hydrogen bonds and quasi-Type I/II Cl⋯F halogen⋯halogen bonds are observed, while adjacent dimethyl sulfoxide mol-ecules form S⋯O chalcogen-bonded chains.
Authors
- David B. Cordes (ORCID: https://orcid.org/0000-0002-5366-9168)
- Aidan P. McKay (ORCID: https://orcid.org/0000-0002-8578-7054)
- Mohd Abdul Fatah Abdul Manan (ORCID: https://orcid.org/0000-0001-9992-0306)
Institutions
- University of St Andrews (GB)
- Universiti Teknologi MARA (MY)
Publication Details
- Journal
- IUCrData
- Published
- 2025-10-03
- DOI
- https://doi.org/10.1107/s2414314625008491
- Primary Topic
- Synthesis and Reactions of Organic Compounds
- Type
- article
- Field-Weighted Citation Impact
- 0.00